Ultraviolet
(UV) radiation is electromagnetic radiation of a wavelength
shorter than that of visible light, but longer than
that of soft X-rays. The name means "beyond violet" (from
Latin ultra, "beyond"), violet being the color of the
shortest wavelength of visible light. It is colloquially called
black light, as it is invisible to the human eye.
UV itself can be subdivided into near UV (380-200 nm wavelength)
and extreme or vacuum UV (200-10 nm). When considering the effects
of UV radiation on human health and the environment, the range
of UV wavelengths is often subdivided into UV-A (380-315 nm),
UV-B (315-280 nm), and UV-C (280-10 nm). See 1 E-7 m for a list
of objects of comparable sizes.
Ordinary glass is transparent to UV-A but is opaque to shorter
wavelengths. Quartz glass, depending on quality, can be transparent
even to vacuum UV wavelengths.
The sun emits ultraviolet light in the UV-A, UV-B, and UV-C
bands, but because of absorption in the atmosphere's ozone layer,
99% of the ultraviolet light that reaches the Earth's surface
is UV-A. (Some of the UV-C light is responsible for the generation
of the ozone.)
Partial electromagnetic spectrum; scale in nanometers
Ultraviolet
Lamps
The principal
ultraviolet light source in use today is based on light emission
from ionized Hg vapor contained in a low-pressure
glass or fused silica tube. As atoms of mercury within these
lamps are excited they emit a very strong light at 253.7nm
(shortwave ultraviolet). This
may be passed through the walls of a fused silica tube (shortwave
ultraviolet does not penetrate glass) and then through a special
dark filter, providing a lamp rich in 254nm shortwave ultraviolet. Other
lamps can be made with varying formulations of phosphors coating
the inside
of the tubes. These absorb the 253nm ultraviolet
and fluoresce in other regions of the ultraviolet spectrum, depending
on the phosphor. In fact, common household ‘fluorescent
lights’ are based on similar technology. In that case,
however, the tube is glass opaque to ultraviolet and the phosphors
inside fluoresce in various parts of the visible spectrum - combined
they appear as white light.
Mineral
collectors use lamps or "blacklights" in the shortwave,
midwave and longwave regions of the ultraviolet; far ultraviolet
does not pass through air very well and is both dangerous and
impractical. Most shortwave lamps in use today emit almost
completely at 254nm
(as below); longwave sources have more variable outputs
dependant on phosphor mix and filtering.
The
two longwave sources we use have tubes with peaks at 352nm
and 368nm (upper right), but other wavelengths are
present as well.
Several
midwave or "UVB" lamps have become
available in recent years, and these also have outputs
dependant
on phosphor mix and filtering.
The one used for midwave photographs on this website has
the spectrum shown at right, which includes a fairly broad
range of wavelengths.
Ilímaussaq
Fluorescence
To best experience
the fluorescent minerals of Ilímaussaq
one should have access to lamps in all three ultraviolet regions.
The local sodalite responds most brightly to longwave or midwave
ultraviolet; while associated fluorescent minerals may glow
best under shortwave. The tenebrescent effect in both sodalite
and
tugtupite is stimulated by shortwave ultraviolet. Tugtupite
glows in different colors under differing ultraviolet sources.
Some
responds with a unique white color under midwave only. A
large display of Ilímaussaq fluorescent minerals would
best have a ‘full spectrum’ of ultraviolet light
sources: short-, mid-, and longwave.
Activators
Some minerals,
like scheelite, are intrinsically fluorescent -
their ideal chemical formula and perfect crystal structure
provide
a fluorescent material.
Most fluorescent minerals
however owe their glow to the presence of minor/trace impurities
or structural
defects. Hence, the fluorescence of
many species is variable; depending on a few ‘alien’ atoms
or structural ‘holes’. At
Ilímaussaq, the late-stage lujavrites are enriched
in volatiles - including S2-. The presence of
minor amounts of sulfur has been identified as the cause of fluorescence in
both sodalite and tugtupite.