The chemistries
of the tungstate ion (WO4)2-, and the molybdate
ion (MoO4)2-,
are so similar that the groups of minerals are always associated,
with extensive solid solution between the two extremes. The anions
are distorted tetrahedra with the central tungsten or molybdenum
atom bonded to four oxygen atoms by largely covalent bonds.
Tungstates
are very important industrial minerals giving rise to tungsten
metal which when alloyed with iron, produces a very
strong corrosion resistant steel. The metal is also extensively
used in the manufacture of filaments for light-bulbs, vacuum
and x-ray tubes.