The sulfides
are complex minerals in both chemistry and origin. They are usually
deposited form aqueous solutions in fault zones of the crust, located
near large igneous bodies called batholiths. Great effort has been
made to understand the origins and properties of the sulfides because
they are amongst the most sought after minerals. Their compounds
give rise to the many metals used by society.
The
sulphides are in essence oxygen-free compounds of sulphur
and one or more metals. In the simplest form the sulfide structure
forms spherical packing of large sulphur atoms with the smaller
metal atoms in the spaces between. The chemical bonding between
metal and sulphur varies in degrees of metallic, ionic and
covalent bonds.
Most sulfides have
a strong metallic appearance, with a strong colour and metallic
lustre. The majority are opaque, have high
densities and many of them are brittle, which easily distinguishes
them from the native metals. Few stand up well to atmospheric
weathering and usually convert to secondary ore minerals.
Sulfides
may be subdivided into the simple compounds of metal with sulphur,
the sulfides, and into compounds of a metal with
sulphur plus a semi-metal such as arsenic, antimony or bismuth.
These are known as sulfosalts. Usually included in this group
are the corrsponding, but much rarer compounds in which the sulphur
is replaced all together by selenium, tellurium, antimony or
bismuth.