A
mineral that has taken the crystal shape of another mineral
is said to be a pseudomorph,
meaning "false form." This
phenomenon can occur in various ways.
The process of pseudomorphism may be mechanical,
structural, or chemical in nature and results from changes
in the physical
and chemical environment during or after the period of initial
crystallization. A pseudomorph is classified both by the nature
of the processes by which it was formed and by the changes
it experienced during those processes. Three mechanisms of
pseudomorphism can be defined as:
Substitution
In this mechanism chemical constituents are simultaneously
removed and replaced by other chemical constituents during
alteration. An example is the replacement of wood fibers by quartz
to form
petrified wood that has the outward appearance of the original
wood, but is composed of quartz. Another example is the alteration
of fluorite which forms isometric crystals and is sometimes
replaced by quartz during alteration. The resulting quartz crystals
look
isometric, and are said to be pseudomorphed after fluorite.
Encrustation
If during the alteration process a thin crust
of a new mineral forms on the surface of a preexisting mineral,
then the preexisting mineral is removed, leaving the crust
behind, we say that pseudomorphism has resulted from encrustation.
In
this case the thin crust of the new mineral will have casts
of the form of the original mineral.
Alteration
If only partial removal of the original mineral
and only partial replacement by the new mineral has taken place,
then it is possible to have a the space once occupied entirely
by the original mineral be partially composed of the new mineral.
The
pseudomorphic change is expressed, for example, as "aragonite
(original mineral) > calcite (later mineral)." Another
way of writing it is "calcite after aragonite."