A mineraloid
is a mineral-like substance that does not demonstrate crystallinity.
Mineraloids possess chemical compositions that lie outside the
generally accepted ranges for specific minerals. For example, obsidian
is a glass and not a crystal.
Jet is a dense form of coal.
By definition,
a mineral has
to have an ordered atomic arrangement, or crystalline structure.
There are some Earth materials that
fit all other parts of the definition of a mineral,
yet do not have a crystalline structure. Such compounds are termed amorphous (without
form).
Some
of these amorphous compounds
are called mineraloids. These usually form at low temperatures
and pressures during the process of chemical weathering
and form mammillary, botryoidal, and stalactitic masses
with widely varying chemical compositions. Limonite [FeO.(OH).nH2O]
and allophane (a hydrous aluminum silicate) are good examples.
Others like volcanic glass and opal (SiO2.nH2O) have short-range
order or domains wherein some crystalline-like order exists.
Unlike crystalline minerals that show sharp, well defined
x-ray diffraction peaks, these mineraloids with short-range
order show broad diffraction peaks that give evidence of
the short-range order.
Mineraloids
meet most, but not all, of the criteria required to be classified
as minerals.
For example, opals (SiO2 . nH2O)
are composed of layers of closely packed silica spheres, with
H2O molecules and additional silica filling the void
spaces between the silica spheres. Common or amorphous, opal
is a mineraloid
because the silica spheres have highly variable sizes and thus
lack a predictable three-dimensional structure. Precious opal,
however, is composed of silica spheres of approximately the same
size, producing a predictable three-dimensional array.
Precious opals formed through the low temperature inorganic precipitation
of colloidal silica from silica-rich waters are classed as minerals;
precious opals formed through the accumulation of siliceous tests
of silica-secreting organisms are not.
The members
of this unofficial class are often mistaken for minerals, but
lack the necessary crystalline structure to be classified as
such. They are found naturally, are often treated as gemstones,
and are included in most mineral references.