The carbonates and related nitrates and borates are common constituents
of the earth's near-surface crust. This is a structurally-related
as well as chemically-related group The basic anionic (negatively
charged) unit of this class consists of a triangle where at the
center resides either a carbon, nitrogen or boron atom. At every
corner of the triangle sits an oxygen atom. The threefold symmetry
of the triangle explains the trigonal symmetry that many members
of this class possess. As long as the triangles of the anionic
group fall in a plane parallel with the plane of the triangle and
all other bonds in the structure, when viewed perpendicular to
this plane, are multiples of three, and are evenly separated from
each other, the mineral will have a trigonal symmetry.
Although somewhat varied, this class' properties can be generalized
more so than the other classes. Typical carbonates are transparent,
lightly colored with a white streak, average to above average
in density, soft with good to perfect cleavage, soluble to at
least some degree in acidic solutions, and tend to originate
in sedimentary and oxidizing environments with the exception
of carbonatite igneous intrusions. Most of these common characteristics
are due to the common chemistry the group shares and members
that diverge from the norm do so because of the effects of metal
cations such as lead, copper, manganese and iron.
Carbon
dioxide in the air dissolves in water to form carbonic acid H2CO3,
consisting of hydrogen ions H 1+ and bicarbonate (HCO3) ions.
If conditions of concentration and temperature are favourable,
the carbonate ion will combine with metal ions to form carbonates.
The stucture of these inorganic salts consists of triangular (CO3)2- ions held together by the metal ions in a crystalline lattice.
The (CO3)2- groups are otherwise isolated in the structure and
do not form chains, rings or layers. Of the nearly 70 carbonate
minerals, only calcite and dolomite are commonly found species.
These are important minerals in sedimentary rocks such as chalk
and limestone, and metamorphic rocks like marble. They are also
common in hydrothermal veins.