All atoms have a strong tendency to achieve a stable
configuration of the outer electron shell in which all possible electron
sites are filled. This is why bonding takes place. This means that
the forces that bond cyrstals together are electrical in nature.
The type and intensity of bonding are responsible for the physical
and chemical properties of minerals. Hardness, cleavage, fusibility
(to become liquid or plastic), electrical and thermal conductivity,
and thermal expansion are directly related to bonding forces. In general,
the stronger the bond the harder the crystal, the higher its melting
point, and the smaller its thermal expansion. Diamond is so hard because
of the very strong electrical forces linking its carbon atoms.
Molecular:
Recognizable molecules in the structure and the crystal
are held together by non-covalent interactions like van der Waals
forces or hydrogen bonding. The van der Waals' weak bond ties neutral
molecules into a lattice and is the weakest of the chemical bonds.
This type of bond is
not often found in minerals.
Van der Waals'-bonded minerals are characterized
by:
An example is the mineral graphite, which consists of covalent
bonded sheets of carbon atoms linked only by van der Waals' bonds.
This is
what gives graphite a slippery feel.
Metallic:
In metallic bonding the electons are very weakly tied
into the metal structure. An electron owes no allegiance
to any
particular nucleus
and is free to drift through the structure.
Metallic-bonded minerals are characterized by:
High
placticity, tenacity, ductility, and conductivity
Among minerals, only the native metals display pure metallic
bonding.
Ionic:
In ionic bonding the ions are joined together in the cyrstal
structure by the attraction of their unlike electrostatic
charges. One ion has a negative charge, the other a positive
charge.
Because the electrostatic charge is spread over the whole
surface of the atom, this bond type is not highly
directional and the symmetry
of the resulting crystal is generally high.
Covalent:
Covalent bonding is described as a sharing
of electrons. It is the strongest
of the chemical bonds.
Covalent-bonded minerals are characterized
by:
Insolubility
Great
stability
Very
high melting and boiling points
Nonconductors of electricity, the bond is highly directional
and the symmetry of the resulting crystal is
likely to be lower than
where ionic bonding occurs.